Molybdenum(0)-Catalyzed Tandem Cyclization Reactions of Aminoalkynes with Diketones for Multiply Substituted Azaheterocycles
Authors:
Journal: Palash Mondal, Poulami Dutta, Ganesan Mani, The Journal of Organic Chemistry, https://doi.org/10.1021/acs.joc.6c01148 Year: 2026 Posted: 30 Jul 2026
Dipyrromethane-diphosphines: nickel and palladium complexes as catalysts for the selective hydroboration of CO2 to methoxyborane under mild conditions with mechanistic study
Authors:
Vol: Pages: accepted
Journal: Rohit Gupta, Ashok Kumar and Ganesan Mani, RSC Advances, 2026, DOI: 10.1039/D6RA04348H Year: 2026 Posted: 29 Jul 2026
The Hydroboration of CO2 with 9-BBN to Methoxyborane Catalyzed by Pincer Carbene Palladium(II) and Nickel(II) Thiolates with High Turnover Numbers.
Authors:
Journal: Kumar, K.; Gupta, R.; Mani, G. Organometallics, 2026, 45, 410–423. Year: 2026 Posted: 24 Jul 2026
Synthesis and Structural Characterizations of Self-Assembled Silver(I) Complexes of the Pyrazole Ligands: Effect of anion and VT NMR Study.
Authors:
Journal: Mondal, M.; Mani, G. Polyhedron, 2026, 284, 117910. Year: 2026 Posted: 24 Jul 2026
The DMSO-Catalyzed CO2 Reduction with 9-BBN as a Source for the Selective N-Formylation, Room Temperature N-Methylation of Amines, N-Hydroxymethylation of Heterocycles, and C–N Couplings.
Authors:
Journal: Kumar, A.; Gupta, R.; Mani, G. J. Org. Chem. 2025, 90, 10316–10331 Year: 2025 Posted: 24 Jul 2026
Mo(0) carbonyl complexes bearing the bis(3,5-dimethylpyrazole) ligand: Catalysis of the regioselective [2+2+2] cycloaddition of terminal alkynes to synthesize 1,3,5-isomer.
Authors:
Journal: Mondal, P.; Dutta, P.; Mani, G. Dalton Trans., 2025, 54, 2654-2663 Year: 2025 Posted: 24 Jul 2026
DMSO-catalyzed CO2 reduction with 9-BBN: selective formation of either formoxy- or methoxyborane under mild conditions and C-methylenation of indoles.
Authors:
Journal: Kumar, A.; Gupta, R.; Subramaniyan, V.; Mani, G. Catal. Sci. Technol, 2025, 15, 678-688 Year: 2025 Posted: 24 Jul 2026
Selective synthesis of the missing tiara-like Ni10, Ni5 and Ni6 thiolates by the C-S bond cleavage of bis(thioether) molecules with DFT study
Authors:
Journal: Debnath, S.; Giri, S.; Mani, G. Dalton Trans., 2024, 53, 14875-14886 Year: 2024 Posted: 24 Jul 2026
Copper(I) Complexes Bearing the Pyrrole-Bridged S,N and N-Donor Ligands as Catalysts for the Tandem Hydroamination-Alkynylation: Effect of Anions on Product Formation
Authors:
Journal: Mondal, M.; Mani, G. Dalton Trans., 2024, 53, 13996 - 14010 Year: 2023 Posted: 24 Jul 2026
Dipyrromethane–diphosphine:the effect of meso substituents on the formation of nickel complexes and on their performance in the transfer hydrogenation of ketones
Authors:
Journal: Gupta, R.; Kumar, A.; and Mani, G. Dalton Trans. 2023, 52, 18332-18341 Year: 2023 Posted: 24 Jul 2026
PCP Pincer Carbene Nickel(II) Chloride, Hydride, and Thiolate Complexes: Hydrosilylation of Aldehyde, Ketone, and Nitroarene by the Thiolate Complex
Authors:
Journal: Kumar, A.; Gupta, R.; and Mani, G. Organometallics 2023, 42, 732?744 Year: 2023 Posted: 24 Jul 2026
Four- and five-coordinate nickel(II) complexes bearing new diphosphine-phosphonite and triphosphine-phosphite ligands: catalysts for N-alkylation of amines.
Authors:
Journal: Panigrahi, D.; Mondal, M.; Mani, G. RSC Adv., 2022, 12, 4510-4520 Year: 2022 Posted: 24 Jul 2026
Synthesis, structural characterization, and bonding analysis of two-coordinate copper(I) and silver(I) complexes of the pyrrole-based bis(phosphinimine): new metal-pyrrole ring ? interactions
Authors:
Journal: Dalton Trans., 2021, 50, 8036-8044. Year: 2021 Posted: 24 Jul 2026
Synthesis and Structural Characterizations of Pd(II) Complexes Bearing the New Hexahydropyrimidine and Tetrahydropyrimidinium Based Bis(pyrazole) Ligands with DFT Studies
Authors:
Journal: J. Mol. Struc., 2021, 1231, 129949 Year: 2021 Posted: 24 Jul 2026
Versatility of the bis(iminopyrrolylmethyl)amine ligand: tautomerism, protonation, helical chirality, and secondary coordination sphere with halogen bonds in the formation of copper(II) and nickel(II) complexes
Authors:
Journal: Dalton Trans., 2020, 49, 13840 Year: 2020 Posted: 24 Jul 2026
New Spiro-borane and Spiro-borate Derived from Dipyrromethane and their H/D Exchange Properties
Authors:
Journal: Polyhedron, 2020, 186, 114612 Year: 2020 Posted: 24 Jul 2026
Synthesis, X?Ray Structures, and Fluxional Properties of Symmetrical, Asymmetrical Binuclear and Cubane Type Copper(I) Complexes Bearing the Pyrrole-Based P, N-Hetero Donor Ligand
Authors:
Journal: ChemistrySelect, 2020, 5, 5006-5012 Year: 2020 Posted: 24 Jul 2026
Mannich Reaction of Pyrrole and Dimethylpyrrole with Monoamines and Diamines
Authors:
Journal: Tetrahedron Lett., 2019, 60, 151247 Year: 2019 Posted: 24 Jul 2026
Mixed Ligand Cu(II) Complexes: Square Pyramidal vs Trigonal Bipyramidal with the Pyrrole-based Dipodal Ligand Having Hydrogen Bond Acceptors
Authors:
Journal: J. Mol. Struct., 2019, 1195, 1-9 Year: 2019 Posted: 24 Jul 2026
Crystal Structure and DFT Analyses of a Penta-coordinated PCP Pincer Nickel(II) Complex.
Authors:
Journal: Acta Cryst. 2019, C75, 734–739 Year: 2019 Posted: 24 Jul 2026
Nickel(II) and Palladium(II) Complexes Bearing an Unsymmetrical Pyrrole-based PNN Pincer and their Norbornene Polymerization Behaviors Versus the Symmetrical NNN and PNP Pincers
Authors: Das, S.; Subramaniyan, V.; Mani, G.
Journal: Inorg. Chem., 2019, 58, 3444–3456 Year: 2019 Posted: 23 Jul 2026
Homoleptic and Heteroleptic Copper(I) Complexes Bearing Diimine-Diphosphine Ligands, Chapter 8 in ‘Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles’
Authors: Mani, G.; Subramaniyan, V.
Journal: Elsevier Publications, 2019, 237-258 Year: 2019 Posted: 23 Jul 2026
Facile Synthesis of Pd(II) and Ni(II) Pincer Carbene Complexes by the Double C-H Bond Activation of a New Hexahydropyrimidine-Based Bis(phosphine): Catalysis of C-N Couplings
Authors: Subramaniyan, V.; Dutta, B.; Govindaraj, A.; Mani, G.
Vol: 48 Pages: 7203 - 7210
Journal: Dalton Transactions, 2019, 48, 7203 - 7210 Year: 2019 Posted: 24 Jun 2019
Synthesis, Reactions, and Structures of Heterocycle-Tethered Boranes and Their Precursors
Authors: Subramaniyan, V.; Mani, G.
Journal: Organometallics, 2018, 37, 127?135. Year: 2018 Posted: 22 Dec 2018
The `Reverse Transmetalation` Reaction of the Pyrrole-Based PNP Pincer Ni(II) Complexes: X-ray Structures of Binuclear Silver(I) and Thiocyanate Nickel(II) Complexes.
Authors: Kumar, S.; Jana, O.; Subramaniyan, V.; Mani, G.
Journal: Inorg. Chim. Acta. 2018, 480, 113. Year: 2018 Posted: 22 Dec 2018
Enantiomers and Structural Isomers of Sodium and Palladium Complexes Bearing ortho-Bis(3,5-dimethylpyrazolylmethyl)phenolate: Fluxional Propertyand Highly Active Catalysts for Norbornene Polymerization.
Authors: Jana, O.; Mani, G.
Journal: Inorg. Chem. 2018, 57, 7735- 7747. Year: 2018 Posted: 22 Dec 2018
The pyrrole ring n2-hapticity bridged binuclear tricarbonyl Mo(0) and W(0) complexes: catalysis of regioselective hydroamination reactions and DFT calculations
Authors: Jha,V. K.; Mani, G.; Davuluri, Y. R;. Anoop, A.
Journal: Dalton Trans., 2017, 46, 1840-1847. Year: 2017 Posted: 22 Dec 2018
New types of Cu and Ag clusters supported by the pyrrole-based NNN-pincer type ligand
Authors: Jana, O.; Mani, G.
Journal: New J.Chem., 2017, 41, 9361. Year: 2017 Posted: 22 Dec 2018
Regioselective Mannich bases of pyrrole-2-carbaldehyde and binuclear copper(II) complexes of bis(iminopyrrolyl) ligand containing the piperazine ring
Authors: Kumar, R.; Paul, T.; Jana, O.; Mani, G.
Journal: Inorg. Chim. Acta. 2016, 445, 70-78. Year: 2016 Posted: 22 Dec 2018
Synthesis and structural characterization of anion complexes with azacalix[2]dipyrrolylmethane: effect of anion charge on the conformation of the macrocycle
Authors: Guchhait, T.; Mani, G.; Schulzke, C.
Journal: Dalton Trans. 2016, 45, 11781 - 11790. Year: 2016 Posted: 22 Dec 2018
Exhibition of the Bronsted acid-base character of a Schiff base in
palladium(II) complex formation: lithium complexation, fluxional properties and catalysis of Suzuki reactions in water
Authors: Kumar, R.; Mani, G.
Journal: Dalton Trans., 2015, 44, 6896–6908. Year: 2015 Posted: 22 Dec 2018
Synthesis and structural characterization of silver(I), copper(I) coordination polymers and a helicate palladium(II) complex of dipyrrolylmethane-based dipyrazole ligands: the effect of meso substituents on structural formation
Authors: Guchhait, T.; Barua, B.; Biswas, A.; Basak, B.; Mani, G.
Journal: Dalton Trans., 2015, 44, 9091-9102. Year: 2015 Posted: 22 Dec 2018
Self Assembled Macrobicycle and Tricycle Cages Containing
Pyrrole Rings by Dynamic Covalent Chemistry Method
Authors: Jana, D.; Das, S.; Mani, G.
Journal: J. Incl. Phenom. Macrocycl. Chem. 2015, 82, 461-470. Year: 2015 Posted: 22 Dec 2018
Synthesis and structural characterization of chromium(III) complexes
bearing 3,5-dimethylpyrazolate ligand
Authors: Kumar, S.; Mani, G.
Journal: Polyhedron, 2015, 99, 47-52. Year: 2015 Posted: 22 Dec 2018
Structural Diversity of Copper(I) Complexes Formed by Pyrrole- and Dipyrrolylmethane-Based Diphosphine Ligands with Cu–X···HN
Hydrogen Bonds
Authors: Kumar, S.; Mani, G.; Dutta, D.; Mishra, S.
Journal: Inorg. Chem. 2014, 53, 700–709. Year: 2014 Posted: 22 Dec 2018
Single-Step Substitution of all the alpha, beta-Positions in Pyrrole: Choice of Binuclear versus Multinuclear Complex of the Novel Polydentate Ligand
Authors: Ghorai, D.; Mani, G.
Journal: Inorg. Chem., 2014, 53, 4117-4129. Year: 2014 Posted: 22 Dec 2018
Unsubstituted quinoidal pyrrole and its reaction with oxygen, charge transfer and palladium(II) complexes via DDQ oxidation
Authors: Ghorai, D.; Mani, G.
Journal: RSC Adv., 2014, 4, 45603-45611. Year: 2014 Posted: 22 Dec 2018
The syn and anti isomers of the porphyrinogen-like precursor of calix[4]phyrin: isolation, X-ray structure, anion binding and fluoride-ionmediated proton–deuterium exchange studies
Authors: Guchhait, T.; Jha, V. K.; Mani, G.
Journal: Org. Biomol. Chem., 2013, 11, 2818-2826. Year: 2013 Posted: 22 Dec 2018
Synthesis of Novel Polyazacryptands for Recognition of
Tetrahedral Oxoanions and Their X-ray Structures
Authors: Jana, D.; Mani, G.; Schulzke, C.
Journal: Inorg. Chem. 2013, 52, 6427–6439. Year: 2013 Posted: 22 Dec 2018
Mononuclear, helical binuclear palladium and lithium
complexes bearing a new pyrrole-based NNN-pincer ligand: fluxional property
Authors: Ghorai, D.; Kumar, S.; Mani, G.
Journal: Dalton Trans. 2012, 41, 9503-9512. Year: 2012 Posted: 22 Dec 2018
Synthesis and X-ray Structures of Novel Macrocycles
and Macrobicycles Containing N,N-Di(pyrrolylmethyl)-N-methylamine Moiety: Preliminary
Anion Binding Study
Authors: Kumar, R.; Guchhait, T.; Mani, G.
Journal: Inorg. Chem. 2012, 51, 9029–9038. Year: 2012 Posted: 22 Dec 2018
A Tripyrrolylmethane-Based
Macrobicyclic Triazacryptand: X-ray Structure, Size-Selective Anion Binding, and
Fluoride-Ion-Mediated Proton–Deuterium Exchange Studies
Authors: Guchhait, T.; Mani, G.; Schulzke, C.; Anoop, A.
Journal: Inorg. Chem. 2012, 51, 11635–11644. Year: 2012 Posted: 22 Dec 2018
Pyrrole-Based New Diphosphines: Pd
and Ni Complexes Bearing the PNP Pincer Ligand
Authors: Kumar, S.; Mani, G.; Mondal, S.; Chattaraj, P. K.
Journal: Inorg. Chem. 2012, 51, 12527-12539. Year: 2012 Posted: 22 Dec 2018
Synthesis and structural characterization of Pd(II) complexes
containing 2,6-bis[(dimethylamino)methyl]-4-methylphenolate ligand
Authors: Ghorai, D.; Mani, G.
Journal: Inorg. Chim. Acta. 2011, 372, 412-416. Year: 2011 Posted: 22 Dec 2018
Dipyrrolylmethane-based Macrobicyclic Azacryptand: Synthesis,
X-ray Structures, Conformational and Anion Binding Properties
Authors: Guchhait, T.; Mani, G.
Journal: J. Org. Chem. 2011, 76, 10114-10121. Year: 2011 Posted: 22 Dec 2018
Azatripyrrolic and Azatetrapyrrolic Macrocycles
from the Mannich Reaction of Pyrrole: Receptors for Anions,
Authors: Mani, G.; Jana, D.; Kumar, R.; Ghorai, D.
Journal: Org. Lett. 2010, 12, 3212– 3215. Year: 2010 Posted: 22 Dec 2018
Macrocyclic and Acyclic Molecules
Synthesized from Dipyrrolylmethanes: Receptors for Anions,
Authors: Mani, G.; Guchhait, T.; Kumar, R.; Kumar, S.
Journal: Org. Lett. 2010, 12, 3910– 3213. Year: 2010 Posted: 22 Dec 2018
Monodisperse Thioether- Stabilized
Palladium Nanoparticles: Synthesis, Characterization, and Reactivity,
Authors: Ganesan, M,; Freemantle, R. G.; Obare, S. O.,
Journal: Chem. Mater., 2007, 19, 3464-3471. Year: 2007 Posted: 22 Dec 2018
Di- and tri-nuclear molybdenum-palladiumcomplexes bearing strong pi-acceptor
Authors: Ganesan, M, Krishnamurthy S.S, Nethaji M.,
Journal: J. Organomet. Chem. 2005, 690, 1080-1091. Year: 2005 Posted: 22 Dec 2018
Synthesis, structure and catalytic properties of
[Cp*Cr(C6F5)(Bn)(THF)] toward ethylene in the presence of AlEt3
Authors: Ganesan, M.; Gabbai, F.P.
Journal: J. Organomet. Chem. 2005, 690, 5145-5149. Year: 2005 Posted: 22 Dec 2018
A neutral chromium(III) catalyst for the living "Aufbaureaktion"
Angew.
Authors: Ganesan, M.; Gabbaï, F.P.
Journal: Chem. Int. Ed. Engl. 2004, 43, 2263-2266. Year: 2004 Posted: 22 Dec 2018
[Cp*Cr(C6F5)(Me)(Py)] as a Living Chromium(III) Catalyst for
the "Aufbaureaktion"
Authors: Ganesan, M.; Gabbai, F.P.
Journal: Organometallics, 2004, 23, 4608-4613. Year: 2004 Posted: 22 Dec 2018
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